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• W1986282920 endingPage "133" @default.
• W1986282920 startingPage "125" @default.
• W1986282920 abstract "Abstract Ce-doped Ni, Mg and Al hydrotalcites were synthesized through the reconstruction method in the presence of the [Ce(EDTA)] − complex. The hydrotalcites and the mixed oxides derived after their thermal decomposition at 500 °C (16 h) were characterized by XRD, TGA-DTA, ICPS, IR, Raman, SEM-EDX, TEM, TPR-H 2 , TPD-CO 2 , XPS and N 2 sorptometry. The reconstruction of the mixed oxide is not total in [Ce(EDTA)] − solutions with Ce between 1 and 10%wt. The hydrotalcite is reconstructed as hydroxyl-type phase; the reconstruction takes place in the external edges of the oxide granules. The complex is deposited, with high distribution, on the external surface of the reconstructed layered structure as species of Ce 4+ and after the calcination generates surface CeO 2 -doped periclase oxides. Solids were used in the production of syngas through CO 2 reforming of methane (CH 4 :CO 2 :Ar 5/5/40) using a total fixed flow of 50 mL min −1 and WHSV = 30 L g −1  h −1 between 500 and 800 °C with prior reduction. The increase in the Ce load had a promoter effect in catalytic conversions. H 2 /CO ratios between 0.8 and 1.2 were obtained. Ce had a positive effect in the elimination of coke, since a nominal optimal value of 3%wt. was obtained." @default.
• W1986282920 created "2016-06-24" @default.
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• W1986282920 date "2010-04-01" @default.
• W1986282920 modified "2023-10-03" @default.
• W1986282920 title "Syngas production from CO2 reforming of methane using Ce-doped Ni-catalysts obtained from hydrotalcites by reconstruction method" @default.
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• W1986282920 doi "https://doi.org/10.1016/j.apcata.2010.01.037" @default.
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