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- W1986333492 abstract "We report an aqueous one-pot reaction chemistry to derivatize phosphopeptides by switching the negatively charged phosphate group to a positively charged phosphonium or ammonium moiety. The phosphonium or ammonium tagged peptides then serve as peptide or protein phosphorylation signatures allowing extended and more sensitive analyses using surface-enhanced Raman spectroscopy (SERS) and mass spectrometry. Keywords: phosphopeptides • charge switching • β-elimination • Michael addition • phosphonium or ammonium tagged peptides • surface-enhanced Raman spectroscopy (SERS) • mass spectrometry" @default.
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- W1986333492 date "2007-06-21" @default.
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- W1986333492 title "Charge Switch Derivatization of Phosphopeptides for Enhanced Surface-Enhanced Raman Spectroscopy and Mass Spectrometry Detection" @default.
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- W1986333492 doi "https://doi.org/10.1021/pr0606225" @default.
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