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- W1986343332 abstract "We report the observation of size dependent structural disorder by x-ray absorption near-edge spectroscopy (XANES) in InAs and CdSe nanocrystals 17--80 AA{} in diameter. XANES of the In and Cd ${M}_{4,5}$ edges yields features that are sharp for the bulk solid but broaden considerably as the size of the particle decreases. FEFF7 multiple-scattering simulations reproduce the size dependent broadening of the spectra if a bulklike surface reconstruction of a spherical nanocrystal model is included. This illustrates that XANES is sensitive to the structure of the entire nanocrystal including the surface." @default.
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- W1986343332 date "1999-10-25" @default.
- W1986343332 modified "2023-10-03" @default.
- W1986343332 title "Structural Disorder in Colloidal InAs and CdSe Nanocrystals Observed by X-Ray Absorption Near-Edge Spectroscopy" @default.
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- W1986343332 doi "https://doi.org/10.1103/physrevlett.83.3474" @default.
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