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- W1986365384 abstract "A high-surface-area (190 m2/g) amorphous aluminum trifluoride material (“plasma-AlF3”) was synthesized by plasma decomposition of zeolite, and its structural and reactivity properties were investigated. High-resolution transmission electron microscopy of plasma-AlF3 indicates morphological features on the nanometer-scale, whereas temperature-programmed X-ray diffraction is used to determine the phase-transition temperatures of plasma-AlF3 to β- and α-AlF3. Halogen-exchange reactivity is studied by temperature-programmed reaction (TPR) techniques using the dismutation of CCl2F2 as a model reaction. Plasma-AlF3 is found to possess an unexpected low-temperature (>315 °C) activity not observed with the well-known halogen-exchange catalyst β-AlF3. Supporting TPR studies on aluminum trifluoride hydrates are performed to correlate this new activity with an amorphous AlF3 structure, and a simple Lewis acid model is presented to explain the reactivity data." @default.
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- W1986365384 date "2007-01-20" @default.
- W1986365384 modified "2023-10-15" @default.
- W1986365384 title "Temperature-Dependent Halogen-Exchange Activity Studies of Zeolite-Derived Aluminum Trifluoride" @default.
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- W1986365384 doi "https://doi.org/10.1021/cm062034x" @default.
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