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• W1986417256 abstract "Abstract Studies of the interactions of phenyl isocyanate with SnX4 (X = Cl, Br, I) in carbon tetrachloride solution, at ambient temperature, and of the solid products isolated are reported. SnCl4 and SnBr4 yielded 1:2 adducts with C6H5NCO, under these experimental conditions. These complexes were characterized as octahedral trans-[SnX4(OCNC6H5)2]; the two phenyl isocyanate ligands are oxygen-bonded to the Sn4+ ion and occupy trans positions, relative to each other, in the first coordination sphere of this metal ion. Stabilization of the cis-isomers in the solid state is apparently sterically hindered, owing to the presence of the bulky phenyl substituent in the C6H5NCO ligand. The interaction of SnI4 with phenyl isocyanate resulted in the formation of reaction rather than addition products. A solid precipitate, formed in low yield, appears to be a mixture of organic compounds and a tin complex. The N:O (2:1) and Sn:I (1:1) atomic ratios in this precipitate, in combination with the infrared evidence, suggest that the reaction proceeds via either insertion of C6H5NCO between SnI bonds or partial ionization of SnI4 in the presence of the organic ligand, while the organic components of the solid product are mixtures or reaction products of C6H5NCO and phenylimido(C6H5N) group derivatives." @default.
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• W1986417256 date "1979-01-01" @default.
• W1986417256 modified "2023-09-27" @default.
• W1986417256 title "Phenyl isocyanate interactions with tin(IV) halides" @default.
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• W1986417256 doi "https://doi.org/10.1016/s0020-1693(00)95523-3" @default.
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