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- W1986425023 endingPage "3928" @default.
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- W1986425023 abstract "The decrease in the forward rate of the (H2, H2) reaction from its equilibrium value due to the perturbation of the vibrational distribution function by reaction is calculated from a numerical solution of a non‐linear Master equation. The inelastic and reactive cross sections that are required for this calculation were obtained from a Monte Carlo average of many quasiclassical collision trajectories. At 3200°K, the highest temperature studied, the decrease in the equilibrium rate of reaction was 0.21%. The vibrational relaxation time for H2 in the absence of reaction was also calculated and found to obey a Landau‐Teller temperature dependence (Pτ)calc=62× 10−9 exp (148/T1/3) atm·sec. over the range 1200–3200°K." @default.
- W1986425023 created "2016-06-24" @default.
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- W1986425023 date "1972-11-01" @default.
- W1986425023 modified "2023-10-18" @default.
- W1986425023 title "Vibrational Nonequilibrium Effects in the (H<sub>2</sub>, H<sub>2</sub>) Reactive System" @default.
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- W1986425023 doi "https://doi.org/10.1063/1.1678863" @default.
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