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- W1986442372 abstract "Abstract It was empirically established previously that the relation γ 2 /γ 1 in the basic equation of gas chromatography could be substituted in some cases by V mol 2 / V mol 1 . Difficulties in the calculation of γ 2 /γ 1 have been overcome, as the new equation involves only physicochemical parameters of the solutes. The relation r exp 1,2 / r calc 1,2 is used as a measure of the specificity of phases which is related to hydrogen bonding of structure, but not of that due to differences in V mol . These properties of the phase could be evaluated by means of suitable standard solutes. The specificity of some phases for n -paraffins, aromatic hydrocarbons and chlorinated hydrocarbons, and its application to some simple calculations are discussed." @default.
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- W1986442372 date "1974-04-01" @default.
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- W1986442372 title "Evaluation of the specificity of the stationary phase in gas chromatography" @default.
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- W1986442372 doi "https://doi.org/10.1016/s0021-9673(01)97889-6" @default.
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