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- W1986465713 abstract "Abstract With the aid of the Yamaoka mechanism and a.c. polarographic observables, rate constants for the homogeneous reduction of Co(III)pentammine complexes by Eu(II) are measured. Where comparison is possible, rate parameters obtained by this electrochemical procedure are found to be in good agreement with previous measurements by stopped-flow and pulse radiolysis procedures, with one exception. The order of reactivity for the halopentammineCo(III) complexes is found to follow the sequence RF 2+ >RCl 2+ >RBr 2+ >RI 2+ , where R=Co(III)(NH 3 ) 5 3+ . This and a pH dependence noted for the RF 2+ case are suggestive of a predominantly inner sphere reaction pathway." @default.
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- W1986465713 date "1979-04-01" @default.
- W1986465713 modified "2023-09-26" @default.
- W1986465713 title "On the influence of coupled homogeneous redox reactions in d.c. and a.c. polarography" @default.
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- W1986465713 doi "https://doi.org/10.1016/s0022-0728(79)80290-9" @default.
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