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- W1986517829 abstract "Cyclic voltammetry of titanium disulfide electrodes immersed in nonaqueous electrolyte was employed to characterize the potential dependence of the alkali metal ion intercalation; the cyclic voltammetric studies of the nonaqueous Li+, Na+, and K+ electrolytes reveal non‐Nernstian behavior. This irreversible behavior has been attributed either to slow charge transfer or slow solid‐state diffusion. In an attempt to distinguish between these two rate‐limiting processes multiple potential step differential coulometry (MPSDC) was employed to investigate potential dependence of the electrode process under the influence of the solid‐state mass transport effects. The preliminary results of these MPSDC studies indicate that the intercalation reaction is kinetically more reversible than suggested initially by the cyclic voltammetry, but that the charge transfer step is still quite slow. This improvement in the estimated reversibility has been attributed to the minimization of the effect of slow mass transport on the measured electrochemical rate data." @default.
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- W1986517829 date "1982-04-01" @default.
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- W1986517829 title "Electrochemical Investigations of Alkali‐Metal Intercalation Reactions in TiS2: Cyclic Voltammetry and Chronocoulometry of Liquid Electrolyte Systems" @default.
- W1986517829 doi "https://doi.org/10.1149/1.2123950" @default.
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