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- W1986519035 abstract "A total stereo- and enantio-selective synthesis of 2,3-dideoxy-3-C-methylene-d-glycero-pentose and its ethyl furanosides is described. The key reaction of the synthesis is formation of the 3-C-methylene function by catalytic isomerisation of an epoxy alcohol, obtained by silylation of 3-methyl-2-butenal, followed by condensation of the silyl ether with triethyl orthoformate, reduction of the aldehydo group, and Sharpless asymmetric epoxidation of the allylic alcohol. The overall yield is 17% from commercially available 3-methyl-2-butenal as the starting compound." @default.
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- W1986519035 date "1992-02-01" @default.
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- W1986519035 title "Total stereo- and enantio-selective synthesis of 2,3-dideoxy-3-C-methylene-d-glycero-pentose and its ethyl furanosides" @default.
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- W1986519035 doi "https://doi.org/10.1016/0008-6215(92)84097-c" @default.
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