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• W1986592084 abstract "Abstract A novel functional monomer incorporating quinoline derivative moiety as the side group, 2-[4-(2,7,7-trimethyl-3-ethoxycarbonyl-5-oxo-1,4,5,6,7,8-hexhydricquinoline)phenoxyl] ethylmethacrylate (HQPEMA), was synthesized and polymerized utilizing atom transfer radical polymerization (ATRP) technique. 2-(4-Chloromethylphenyl)benzoxazole (CMPB) and CuCl/PMDETA were used as the initiator and catalyst, respectively. GPC, 1 H NMR and fluorescent emission spectroscopy were conducted for characterization of polymers. The linear increase of number average molecular weight ( M n ) versus conversion and the relatively narrow molecular weight distribution ( M w / M n ) of the obtained polymers confirmed that ATRP of HQPEMA was carried out successfully. In addition, the fluorescence “structural self-quenching effect” was observed in the DMF solution of the monomer HQPEMA, which bearing both electron-donating chromophore group and electron-accepting C C bond. We also found that the fluorescence properties of the newly obtained polymers containing quinoline chromophore depended on both the monomer concentration in solution and the polarity of solvents. The emission of the polymer film showed that the emission peak maxima of the polymer film shifted 50 nm towards high wavelength with respect to the polymer in DMF solution due to the intermolecular or intramolecular interactions of the polymer chains." @default.
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• W1986592084 date "2008-06-01" @default.
• W1986592084 modified "2023-09-25" @default.
• W1986592084 title "Atom transfer radical polymerization of a novel quinoline derivative monomer and fluorescent property" @default.
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• W1986592084 doi "https://doi.org/10.1016/j.eurpolymj.2008.01.004" @default.
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