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- W1986616802 abstract "The present paper reports the role of silver nanoparticles, i.e., AgNp (having diameter ∼5–15 nm), in non-covalent interaction between fullerenes (C60 and C70) and a designed bisporphyrin (1) in toluene. UV–Vis measurement reveals reduction in binding constant (K) values for both C60-1 (KC60-1 = 18,800 dm3 mol−1) and C70-1 systems (KC70-1 = 27,300 dm3 mol−1) in presence of AgNp, i.e., KC60-1-AgNp = 3700 dm3 mol−1 and KC70-1-AgNp = 1600 dm3 mol−1 for C60-1-AgNp and C70-1-AgNp nanocomposite, respectively. Dynamic light scattering study reveals considerable increase in the particle size of C70-1-AgNp nanocomposite, i.e., ∼39 nm, compared to C60-1-AgNp, e.g., ∼22 nm. Scanning electron microscope measurement reveals that the well arranged and composed structure of uncomplexed 1 is perturbed very much in presence of both C60 and C70, and it ultimately results into formation of nanoaggregate in case of C70-1-AgNp system. Transmission electron microscope study envisages formation of fibrous structure in presence of C60 and C70." @default.
- W1986616802 created "2016-06-24" @default.
- W1986616802 creator A5054682764 @default.
- W1986616802 creator A5079312227 @default.
- W1986616802 date "2013-10-01" @default.
- W1986616802 modified "2023-10-18" @default.
- W1986616802 title "Inhibition in binding between fullerene and a bisporphyrin in presence of silver nanoparticles in solution: UV–Vis, DLS, SEM and TEM studies" @default.
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- W1986616802 doi "https://doi.org/10.1016/j.saa.2013.04.105" @default.
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