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• W1986699803 abstract "A lyotropic inverse micelle phase composed of water, thermotropic liquid-crystal octylcyanobiphenyl (8CB), and surfactant (DDAB) was studied by using high-resolution calorimetry on several mixtures with 3%, 8%, and 15% micelle concentration. Calorimetric results show strong depression of the isotropic to nematic (I–N) phase-transition temperature. Broad heat-capacity anomalies show the existence of a wide coexistence range of isotropic, nematic, and smectic-A phases, which mimics the behavior of a new nearly stable thermodynamic phase. An observation of the rather sharp almost bulklike nematic to smectic-A (N–A) transition at low-temperatures indicates that our heat capacity results are consistent with the phase separation scenario in which significant number of micelles is expelled during I–N conversion leaving almost pure nematic phase at lower temperatures. It was found that micelles get almost completely remixed on heating the mixture back to the isotropic phase." @default.
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• W1986699803 date "2005-06-08" @default.
• W1986699803 modified "2023-10-17" @default.
• W1986699803 title "Calorimetric study of phase transitions in a liquid-crystal-based microemulsion" @default.
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• W1986699803 doi "https://doi.org/10.1063/1.1927516" @default.
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