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• W1986717466 abstract "Six new Ni(II) complexes of the “heteroscorpionate” ligand (3-tert-butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane, L1OH, have been prepared and characterized (in most cases crystallographically). These complexes include: tetracoordinate [Ni(L1O)Cl]; pentacoordinate [Ni(L1O)(acac)] and [Ni(L1O)(OAc)]; and hexacoordinate [Ni(L1O)(acac)(pz)], [Ni(L1O)(OAc)(MeOH)], and [Ni(L1O)2]. This second generation of heteroscorpionate ligand supports a tetrahedral environment for Ni(II) but is not a tetrahedral enforcer. Thus the tetra- and pentacoordinate species readily add additional ligands to produce 5- and 6-coordinate complexes. The formation of the undesirable, coordinatively saturated, [Ni(L1O)2], “sandwich” complex is only a minor interference in most of these reactions unlike the situation seen with the previous generation of ligand. This family of heteroscorpionates shows promise as platforms for biomimetic studies which are already underway." @default.
• W1986717466 created "2016-06-24" @default.
• W1986717466 creator A5001259857 @default.
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• W1986717466 date "1999-07-01" @default.
• W1986717466 modified "2023-10-12" @default.
• W1986717466 title "The Synthesis and Characterization of 4, 5, and 6 Coordinate Ni(II) Complexes of the “Heteroscorpionate” Ligand (3-<i>tert</i>-Butyl-2-hydroxy-5-methylphenyl)bis(3,5-dimethylpyrazolyl)methane" @default.
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• W1986717466 doi "https://doi.org/10.1021/ic9900962" @default.
• W1986717466 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/11671105" @default.
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