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- W1986762305 abstract "A mild and efficient [3+2] nitrile oxide/olefin cycloaddition allows coupling of the highly functionalized naphthalene and isocoumarin hemispheres of purpuromycin. A rationale of the inability of advanced keto alcohols to spirocyclize is presented based upon a systematic examination of the electronic factors present in these systems and suggests that the biosynthesis of purpuromycin does not proceed through open-chain intermediates." @default.
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- W1986762305 date "2006-06-30" @default.
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- W1986762305 title "Investigation of a Convergent Route to Purpuromycin: Benzofuran Formation vs Spiroketalization" @default.
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- W1986762305 doi "https://doi.org/10.1021/ol061112j" @default.
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