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- W1986763821 abstract "The enrichment of the 13 C isotope by partial photolysis of dibenzyl ketone on silica gel has been demonstrated. The 13 C enrichment is substantial and is parallel to the increase in the probability of geminate radical recombination on a silica surface as compared with that in solution. A substantial 13 C enrichment was also observed for the rearranged starting material, 1-phenyl-4′-methylacetophenone. The single-stage isotope separation factors are different for the two ketones although both are isomers derived from the same benzyl–phenylacetyl radical pairs." @default.
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- W1986763821 date "1984-10-01" @default.
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- W1986763821 title "Surface photochemistry: 13C enrichment by photolysis on silica gel" @default.
- W1986763821 doi "https://doi.org/10.1139/v84-341" @default.
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