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- W1986779053 abstract "Abstract Different solid solutions of PVC in dibutyl phthalate, tritolyl phosphate, diallyl phthalate, and mixture of diallyl phthalate and dibutyl phthalate were subjected to gamma radiation. The chemical, physical and physicomechanical properties of the irradiated samples were investigated. With respect to PVC plasticates in dibutyl phthalate, it was found that the crosslinking reaction is the predominant reaction at doses higher than 0.2 MGy. Furthermore, as the dibutyl phthalate content increases, the degree of crosslinking increases. When PVC was blended with tritolyl phosphate, the extent of change in the samples was reduced. Diallyl phthalate promotes the crosslinking reaction in PVC. It was found that the concentration of diallyl phthalate has no considerable effect on the extent of crosslinking in the range under investigation. PVC plasticates as mixtures of diallyl phthalate and dibutyl phthalate show the same crosslinking percentage as the samples containing diallyl phthalate only (on the same weight basis). This shows that the internal viscosity of PVC has no effect on the conversion of diallyl phthalate." @default.
- W1986779053 created "2016-06-24" @default.
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- W1986779053 date "1986-01-01" @default.
- W1986779053 modified "2023-09-26" @default.
- W1986779053 title "Radiation effects on poly(vinyl chloride). 2. Effect of plasticizers on the behaviour of PVC" @default.
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- W1986779053 doi "https://doi.org/10.1016/1359-0197(86)90049-4" @default.
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