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- W1986913362 abstract "The title compound, [Cu 2 (C 16 H 20 N 6 O 4 )(NO 3 ) 2 (H 2 O) 4 ]·3H 2 O, crystallizes with two dinuclear Cu II complex molecules, each lying on an inversion center, and six solvent water molecules per unit cell. The central 1,6-diazecine ring adopts the common chair conformation invariably found in the family of complexes bearing such ligands. The Cu II atoms have an octahedral geometry, with a very strong tetragonal distortion due to the Jahn–Teller effect. Axial sites are occupied by a nitrate ion and a water molecule. The Cu...Cu separations [7.3580 (9) and 7.3341 (9) Å] are compatible with a potential catecholase activity. Neighboring molecules in the crystal structure are connected via O—H...O hydrogen bonds formed by water molecules and carboxylate O atoms. N—H...O hydrogen bonds are also present." @default.
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- W1986913362 date "2008-08-06" @default.
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- W1986913362 title "[μ-2,8-Dimethyl-1,4,5,6,7,10,11,12-octahydrodiimidazo[4,5-h;4′,5′-c][1,6]diazecine-5,11-diacetato]bis[diaquanitratocopper(II)] trihydrate" @default.
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- W1986913362 doi "https://doi.org/10.1107/s1600536808023969" @default.
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