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- W1986914195 abstract "Abstract Picosecond infrared saturation-recovery measurements have been performed on the OH-stretching vibrations (3500–3710 cm −1 ) of hydroxyl groups located within the octahedral layers of ten naturally occurring crystalline micas. At room temperature, the average OH( v = 1) vibrational population lifetime ( T 1 ) ± σ) for OH − in muscovite is 92 ± 13 ps. For biotite samples, absorptions arising from two distinct lattice sites yield T 1 = 221 ± 23 and 87 ± 33 ps, respectively. Crystal structures, hydroxyl orientation and hydrogen bonding, ionic environment and infrared Spectroscopy of these mineral families are used to rationalize the observed relaxation times." @default.
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- W1986914195 date "1986-08-01" @default.
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- W1986914195 title "Vibrational population lifetimes of OH(v = 1) in natural crystalline micas" @default.
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- W1986914195 doi "https://doi.org/10.1016/0009-2614(86)80166-x" @default.
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