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• W1986919803 abstract "Significance Repeated modification of a multisite protein plays a key role in cell signaling. After an enzyme catalyzes a reaction at one site, it can modify another site before diffusing away. This physical process, which is amplified in the crowded environment of the cell, has been recently shown by stochastic simulations of hundreds of particles to dramatically change the response of a biochemical network. Here we show that the influence of diffusion on multisite protein modification can be described in a much simpler way, by introducing new connections into the kinetic scheme with rates depending on the probability that an enzyme–substrate pair diffuses apart rather than reacts. Our approach is applicable to complex reaction networks." @default.
• W1986919803 created "2016-06-24" @default.
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• W1986919803 date "2013-11-18" @default.
• W1986919803 modified "2023-10-16" @default.
• W1986919803 title "Diffusion modifies the connectivity of kinetic schemes for multisite binding and catalysis" @default.
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• W1986919803 doi "https://doi.org/10.1073/pnas.1319943110" @default.
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