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- W1986936036 abstract "We describe transformations of the Dion–Jacobson (D–J) phases, KLaNb2O7 and RbBiNb2O7, to the Aurivillius (A) phases, (PbBiO2)LaNb2O7 (1) and (PbBiO2)BiNb2O7 (2), in a metathesis reaction with PbBiO2Cl. Oxide 1 adopts centrosymmetric tetragonal structure (a = 3.905(1) Å, c = 25.66(1) Å), whereas oxide 2 crystallizes in a noncentrosymmetric orthorhombic (A21am) (a = 5.489(1) Å, b = 5.496(2) Å, c = 25.53(1) Å) structure. Oxide 2 shows a distinct SHG response towards 1064 nm laser radiation. The role of La3+ versus Bi3+ in the perovskite slabs for the occurrence of noncentrosymmetric structure/ferroic property in these materials is pointed out." @default.
- W1986936036 created "2016-06-24" @default.
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- W1986936036 date "2005-01-01" @default.
- W1986936036 modified "2023-10-17" @default.
- W1986936036 title "Transformation of Dion–Jacobson phase to Aurivillius phase: synthesis of (PbBiO2)MNb2O7 (M=La, Bi)" @default.
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- W1986936036 doi "https://doi.org/10.1016/j.materresbull.2004.09.015" @default.
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