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- W1986979689 abstract "The liquid like→solidlike 2D phase transition of adenine adsorbed at the Hg/ethylene glycol solution interface is here studied. Equilibrium aspects are effectively rationalized by using a model which was originally developed in the case of the 2D phase transition of adenine adsorbed at the Hg/aqueous solution interface [1], [2]. In this work, the attention is mainly focused on the validation of the model itself in the case of a solvent different from water. The results obtained in the two different solvents are then compared in terms of structural (orientation of the adsorbate at the interface) and related thermodynamic (liquidlike→solidlike 2D standard entropy variation) properties. It is also found that the kinetics of formation of the 2D solid like phase follows a nucleation and growth mechanism, again in close similarity with the results obtained in water." @default.
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- W1986979689 date "1990-02-01" @default.
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- W1986979689 title "Phase transition in the adsorption process of N-dansylglycinate anion on mercury" @default.
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- W1986979689 doi "https://doi.org/10.1016/0022-0728(90)85187-a" @default.
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