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- W1986994343 abstract "Ceramic/metal (C/M) {222} MgO/Cu (Ag) heterophase interfaces, prepared by internal oxidation, are studied by scanning transmission electron microscopy (STEM). The observed spacing between misfit dislocations (1.45 nm) in a 〈110〉 projection is in agreement with the prediction of Bollmann's geometric O-lattice theory and experimental values in the literature for {222} MgO/Cu interfaces. It is concluded that the {222} MgO/Cu (Ag) interfaces are semicoherent and contain a trigonal network of pure edge misfit dislocations parallel to 〈110〉-type directions, with an (a/6)〈211〉-type Burgers vector. Misfit dislocations are also found in a standoff position at a distance of a single (111) spacing of the Cu (Ag) matrix. Extra intensity at the interface, in some angular dark-field images indicates silver segregation, in agreement with our atom-probe field-ion microscope results. On the metal side of the interface, extra intensity is observed in five atomic layers, which corresponds to a total silver enrichment of approximately 0.7 effective monolayers." @default.
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- W1986994343 date "1999-11-01" @default.
- W1986994343 modified "2023-10-11" @default.
- W1986994343 title "Atomic-scale structure and chemistry of ceramic/metal interfaces—I. Atomic structure of {222} MgO/Cu (Ag) interfaces" @default.
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- W1986994343 doi "https://doi.org/10.1016/s1359-6454(99)00255-4" @default.
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