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- W1987015973 abstract "The structures of [P,P-diethyl-P'P'-diphenyl-1,2ethanediphosphine-P,P')di(thiocyanato-N)nickel(II), Ni(NCS) 2 (Et 2 PCH 2 CH 2 PPh 2 ) (1), and {bis[2-(diphenylphosphino)ethyl]ethylphosphine-P,P',P''}di(thiocyanato-N)nickel(II), Ni(NCS) 2 [EtP(CH 2 CH 2 PPh 2 ) 2 ] (2), have been determined. Complex (I) has square-planar geometry about Ni defined by the bidentate diphosphine ligand and two N-bonded thiocyanato ions. Thiocyanate coordination is nearly linear, with Ni-N-C angles of 170.2 (2) and 172.4 (2) o . The P-Ni-P bite angle of the chelating Ph 2 P(CH 2 ) 2 PEt 2 ligand is 87.05 (3) o" @default.
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- W1987015973 date "1993-07-15" @default.
- W1987015973 modified "2023-09-25" @default.
- W1987015973 title "Structures of nickel(II) bis- and trisphosphine diisothiocyanate complexes" @default.
- W1987015973 doi "https://doi.org/10.1107/s0108270193000770" @default.
- W1987015973 hasPublicationYear "1993" @default.
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