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- W1987057029 abstract "Abstract A series of donor–π–acceptor systems incorporating a tetrathiafulvalene moiety as the donating unit have been designed and synthesized. The efficiency of the imine (–C=N–) bond as a conjugated π‐linker in promoting intramolecular charge transfer is demonstrated and supported by calculations at the B3LYP/6‐31G(d,p) level of theory. This property has been explored in the case of pyridyl‐substituted systems which exhibit in particular a high binding affinity and selectivity for Pb 2+ (log K = 3.5 in CH 2 Cl 2 /CH 3 CN), as shown by UV/Vis and 1 H NMR titrations as well as by remarkable colorimetric and electrochemical signaling.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)" @default.
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- W1987057029 date "2007-12-18" @default.
- W1987057029 modified "2023-10-17" @default.
- W1987057029 title "Tetrathiafulvalene–Imine–Pyridine Assemblies for Pb<sup>2+</sup> Recognition" @default.
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- W1987057029 doi "https://doi.org/10.1002/ejoc.200700705" @default.
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