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- W1987072753 abstract "Non-chelate control is generally difficult to realize. With the carbenoid 2 it has now been possible for the first time to carry out such an addition (85 % de) of an organolithium compound to the protected lactaldehyde (S)-1. A chiral 1 bromo-l-lithio-l-alkene increases the diastereoselectivity to 95 % de. The product 4 separated the formal after dehalogenation and ozonolysis is formed by the formal addition of ⊖CH2OH." @default.
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- W1987072753 date "1989-07-01" @default.
- W1987072753 modified "2023-10-16" @default.
- W1987072753 title "Non-Chelate-Controlled Addition of 1-Bromo-1-lithio-1-alkenes toO-Protected Lactaldehydes" @default.
- W1987072753 doi "https://doi.org/10.1002/anie.198908961" @default.
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