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- W1987079621 abstract "cis-β1- and β2-8-Quinolinolato or 2-methyl-8-quinolinolato(triethylenetetramine)cobalt(III) complexes, (Remark: Graphics omitted.) (R: H, Me; X: Cl, NO3), have been isolated from a reaction mixture of cis-α-dichloro(triethylenetetramine)cobalt(III) chloride, Ag2O, and 8-quinolinol or 2-methyl-8-quinolinol. The separation of their cis-β and β2 isomers was achieved by the use of ion-exchange resin. The IR spectra of these complexes showed five or six absorption bands in the 990–1100 cm−1 region and four or five absorption bands in the 3000–3300 cm−1 region. This indicates that these complexes assume the β form. In cis-β1-2-methyl-8-quinolinolato(triethylenetetramine)cobalt(III) complexes, the methyl group of the coordinated 2-methyl-8-quinolinolato ligand has a steric hindrance for the NH-side methylene protons of the coordinated trien ligand. On the other hand, no methyl group of the corresponding cis-β2 form has steric hindrance for the methylene protons of the coordinated trien ligand. Therefore, the dis..." @default.
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- W1987079621 date "1983-09-01" @default.
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- W1987079621 title "Cobalt(III) Complexes with Quadridentate Ligands. IV. The Preparation and Properties of “<i>cis</i>-β<sub>1</sub>and β<sub>2</sub>” Isomers of the 2-Methyl-8-quinolinolato(triethylenetetramine)-cobalt(III) and Related Complexes" @default.
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- W1987079621 doi "https://doi.org/10.1246/bcsj.56.2721" @default.
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