FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987131606> ?p ?o ?g. }

• W1987131606 endingPage "261" @default.
• W1987131606 startingPage "257" @default.
• W1987131606 abstract "The thiolate–thiolate exchange reactions between sodium 2-mercaptoethanesulfonate (MES) and 3-mercaptopropionic acid (MPA) and between MES and 2-aminoethanethiol (cysteamine, CYS) are analysed. The monolayers formed on the electrochemically roughened silver substrates from one thiol were exposed to the solution of the other thiol, resulting in rapid replacement of some molecules in the monolayer. The place-exchange reaction of thiols has been studied using surface-enhanced Raman scattering (SERS). SERS measurements revealed that in the rapid initial replacement approximately one-third of chemisorbed thiolate moieties are exchanged. According to the previous investigations of monolayers formed on the flat metal surfaces also about one-third of chemisorbed thiolate moieties exchange rapidly. This phenomenon was ascribed to replacement of thiol moieties at defect sites. Thus, our results suggest that the electrochemical roughening of the metal surface does not significantly increase the number of molecules adsorbed on defects sites in the self-assembled monolayers. Therefore, one can conclude that an average size of “atomically flat” faces on electrochemically roughened SERS active silver surfaces is not smaller than an average size of an individual domain in the self-assembled monolayers formed on the flat metal surfaces. These results also show that thiolates–thiolates exchange procedures used for the preparation of mixed monolayers, which were initially developed and tested on the “flat” metal surfaces, should give similar mixed monolayers if rough SERS-active substrates are used." @default.
• W1987131606 created "2016-06-24" @default.
• W1987131606 creator A5017814816 @default.
• W1987131606 creator A5025643864 @default.
• W1987131606 creator A5028330006 @default.
• W1987131606 date "2005-10-01" @default.
• W1987131606 modified "2023-09-28" @default.
• W1987131606 title "Place-exchange reactions of thiols on electrochemically roughened SERS-active silver" @default.
• W1987131606 cites W1968179860 @default.
• W1987131606 cites W1970722031 @default.
• W1987131606 cites W1971357332 @default.
• W1987131606 cites W1977398427 @default.
• W1987131606 cites W1978669513 @default.
• W1987131606 cites W1980056512 @default.
• W1987131606 cites W1985582172 @default.
• W1987131606 cites W1989329753 @default.
• W1987131606 cites W1990330733 @default.
• W1987131606 cites W1991661839 @default.
• W1987131606 cites W1992962470 @default.
• W1987131606 cites W2012799790 @default.
• W1987131606 cites W2013918333 @default.
• W1987131606 cites W2014548317 @default.
• W1987131606 cites W2017631057 @default.
• W1987131606 cites W2024411601 @default.
• W1987131606 cites W2029836337 @default.
• W1987131606 cites W2039071185 @default.
• W1987131606 cites W2042035790 @default.
• W1987131606 cites W2058096164 @default.
• W1987131606 cites W2068101890 @default.
• W1987131606 cites W2068625016 @default.
• W1987131606 cites W2078985080 @default.
• W1987131606 cites W2080730912 @default.
• W1987131606 cites W2134130835 @default.
• W1987131606 cites W2952200647 @default.
• W1987131606 cites W1974209538 @default.
• W1987131606 doi "https://doi.org/10.1016/j.vibspec.2005.05.002" @default.
• W1987131606 hasPublicationYear "2005" @default.
• W1987131606 type Work @default.
• W1987131606 sameAs 1987131606 @default.
• W1987131606 citedByCount "14" @default.
• W1987131606 countsByYear W19871316062012 @default.
• W1987131606 countsByYear W19871316062014 @default.
• W1987131606 countsByYear W19871316062016 @default.
• W1987131606 countsByYear W19871316062023 @default.
• W1987131606 crossrefType "journal-article" @default.
• W1987131606 hasAuthorship W1987131606A5017814816 @default.
• W1987131606 hasAuthorship W1987131606A5025643864 @default.
• W1987131606 hasAuthorship W1987131606A5028330006 @default.
• W1987131606 hasConcept C120665830 @default.
• W1987131606 hasConcept C121332964 @default.
• W1987131606 hasConcept C131649739 @default.
• W1987131606 hasConcept C147789679 @default.
• W1987131606 hasConcept C150394285 @default.
• W1987131606 hasConcept C169573571 @default.
• W1987131606 hasConcept C17525397 @default.
• W1987131606 hasConcept C178790620 @default.
• W1987131606 hasConcept C179104552 @default.
• W1987131606 hasConcept C185592680 @default.
• W1987131606 hasConcept C188027245 @default.
• W1987131606 hasConcept C2781159505 @default.
• W1987131606 hasConcept C2781324293 @default.
• W1987131606 hasConcept C32909587 @default.
• W1987131606 hasConcept C40003534 @default.
• W1987131606 hasConcept C52859227 @default.
• W1987131606 hasConcept C544153396 @default.
• W1987131606 hasConcept C55493867 @default.
• W1987131606 hasConcept C7070889 @default.
• W1987131606 hasConcept C75473681 @default.
• W1987131606 hasConceptScore W1987131606C120665830 @default.
• W1987131606 hasConceptScore W1987131606C121332964 @default.
• W1987131606 hasConceptScore W1987131606C131649739 @default.
• W1987131606 hasConceptScore W1987131606C147789679 @default.
• W1987131606 hasConceptScore W1987131606C150394285 @default.
• W1987131606 hasConceptScore W1987131606C169573571 @default.
• W1987131606 hasConceptScore W1987131606C17525397 @default.
• W1987131606 hasConceptScore W1987131606C178790620 @default.
• W1987131606 hasConceptScore W1987131606C179104552 @default.
• W1987131606 hasConceptScore W1987131606C185592680 @default.
• W1987131606 hasConceptScore W1987131606C188027245 @default.
• W1987131606 hasConceptScore W1987131606C2781159505 @default.
• W1987131606 hasConceptScore W1987131606C2781324293 @default.
• W1987131606 hasConceptScore W1987131606C32909587 @default.
• W1987131606 hasConceptScore W1987131606C40003534 @default.
• W1987131606 hasConceptScore W1987131606C52859227 @default.
• W1987131606 hasConceptScore W1987131606C544153396 @default.
• W1987131606 hasConceptScore W1987131606C55493867 @default.
• W1987131606 hasConceptScore W1987131606C7070889 @default.
• W1987131606 hasConceptScore W1987131606C75473681 @default.
• W1987131606 hasIssue "2" @default.
• W1987131606 hasLocation W19871316061 @default.
• W1987131606 hasOpenAccess W1987131606 @default.
• W1987131606 hasPrimaryLocation W19871316061 @default.
• W1987131606 hasRelatedWork W1987131606 @default.
• W1987131606 hasRelatedWork W2088106563 @default.
• W1987131606 hasRelatedWork W2099662887 @default.
• W1987131606 hasRelatedWork W2355581207 @default.
• W1987131606 hasRelatedWork W2388833835 @default.
• W1987131606 hasRelatedWork W2765418779 @default.

• next