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- W1987136640 abstract "Abstract Tris(trimethylsilyl)silane ( 2 ) is an efficient hydrosilylating agent of 1,6‐dienes 1 operating via a free‐radical chain mechanism. The intermediate alkyl radical 3 attacks the second olefinic bond of the diene 1 and forms cyclopentylalkyl radical 4 . Using a low concentration of the hydrogen donor 2 , a radical substitution reaction at the Si‐center of cis ‐ 4 occurs and yields the bicyclic silane 6 . The rate of this homolytic substitution at the Si‐atom is 2.4 · 10 5 s ‐1 (80°)." @default.
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- W1987136640 date "1992-05-06" @default.
- W1987136640 modified "2023-10-12" @default.
- W1987136640 title "Homolytic Substitution Reaction at a Silicon Atom" @default.
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- W1987136640 doi "https://doi.org/10.1002/hlca.19920750327" @default.
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