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• W1987167462 abstract "The ground state and protonated state (quaternized salt) vibrational spectra (200–1800 cm−1) of the title amines are reported for various ring and/or methyl deuterated derivatives. Complete assignments are proposed and compared to those established for the parent hydrocarbons, benzene and biphenyl, and for the parent primary amines, aniline, p-phenylenediamine and benzidine. The electronic distribution, N(n)→ring(π) charge-transfer character and inductive effects are characterized from a vibrational point of view. Finally changes in the vibrational and electronic conformation upon protonation of the nitrogen atom are discussed. These results provide a fundamental basis for the vibrational investigation of excited states and reactive transients of aromatic amines." @default.
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• W1987167462 date "1989-01-01" @default.
• W1987167462 modified "2023-10-04" @default.
• W1987167462 title "Vibrational spectra of N,N-dimethyl/diethylaniline, N,N,N′,N′-tetramethyl/tetraethyl-p-phenylenediamine and N,N,N′,N′-tetramethyl/tetraethylbenzidine derivatives" @default.
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• W1987167462 doi "https://doi.org/10.1016/0584-8539(89)80123-0" @default.
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