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- W1987173870 abstract "A stereoselective synthesis of (±)-botryodiplodin is presented. The key reaction is a radical cyclization of a bromoacetal (Ueno-Stork reaction). The stereogenic acetal center has been used to control the stereoselectivity of the process: the difficulty in controlling the stereochemistry at C(3) of the tetrahydrofuran moiety during the cyclization step has been overcome by a double one-pot reduction procedure starting from agem-dibromide.Download : Download full-size image" @default.
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- W1987173870 date "1999-04-01" @default.
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- W1987173870 title "Diastereoselective radical cyclization of bromoacetals: Efficient synthesis of (±)-botryodiplodin" @default.
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- W1987173870 doi "https://doi.org/10.1016/s0040-4039(99)00487-6" @default.
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