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- W1987174304 abstract "The thermal degradation behavior of suspension-polymerized poly(vinyl chloride) (PVC) and ethylene-vinyl chloride copolymer (E-VC) in the early stages was compared by continuous measurement of the extent of dehydrochlorination. The behavior of E-VC was different from that of PVC; the rate of dehydrochlorination of E-VC decreased as a function of heating time whereas that of PVC was constant. It was presumed that the dehydrochlorination reaction was terminated at the ethylene units in the polymer backbone. At a very early degradation stage, however, the rate of dehydrochlorination of E-VC was greater than that of PVC. This degradation behavior arose from structural defects in the polymer, i.e. the content of tertiary chlorine increased according to the increase in ethylene content in E-VC during suspension polymerization." @default.
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- W1987174304 date "1995-04-01" @default.
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- W1987174304 title "Thermal degradation studies of poly(vinyl chloride) and ethylene-vinyl chloride copolymer" @default.
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- W1987174304 doi "https://doi.org/10.1016/0165-2370(94)00848-u" @default.
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