FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987193743> ?p ?o ?g. }

• W1987193743 endingPage "2728" @default.
• W1987193743 startingPage "2718" @default.
• W1987193743 abstract "The reactions of 46 atomic-metal cations with CS2 have been investigated at room temperature using an inductively-coupled plasma/selected-ion flow tube (ICP/SIFT) tandem mass spectrometer. Rate coefficients and products were measured for the reactions of fourth-period atomic ions from K+ to Se+, of fifth-period atomic ions from Rb+ to Te+ (excluding Tc+), and of sixth-period atomic ions from Cs+ to Bi+. Primary reaction channels were observed leading to S-atom transfer, CS2 addition and, with Hg+, electron transfer. S-atom transfer appears to be thermodynamically controlled and occurs exclusively, and with unit efficiency, in the reactions with most early transition-metal cations (Sc+, Ti+, Y+, Zr+, Nb+, La+, Hf+, Ta+, and W+) and with several main-group cations (As+, Sb+) and less efficiently with Se+, Re+ and Os+. Other ions, including most late transition and main-group metal cations, react with CS2 with measurable rates mostly through CS2 addition or not at all (K+, Rb+, Cs+). Traces of excited states (<10%) were seen from an inspection of the observed product ions to be involved in the reactions with Mo+, Te+, Ba+ and Au+ and possibly Pt+ and Ir+. The primary products YS+, ZrS+, NbS+, HfS+, TaS+, WS+, ReS+ and OsS+ react further by S-atom transfer to form MS2+, and TaS2+ reacts further to form TaS3+. CS2 addition occurs with the cations MCS2+, MS+, MS2+, CS2+, and TaS3+ to form M+(CS2)n (n ≤ 4), MS+(CS2)n (n ≤ 4), MS2+(CS2)n (n ≤ 3), (CS2)2+ and TaS3+(CS2). Up to four CS2 molecules add sequentially to bare metal cations and monosulfide cations, and three to disulfide cations. Equilibrium constant measurements are reported that provide some insight into the standard free energy change for CS2 ligation. Periodic variations in ΔG° are as expected from the variation in electrostatic attraction, which follows the trend in atomic-ion size and the trend in repulsion between the orbitals of the atomic cations and the occupied orbitals of CS2." @default.
• W1987193743 created "2016-06-24" @default.
• W1987193743 creator A5039773551 @default.
• W1987193743 creator A5043332857 @default.
• W1987193743 creator A5043954197 @default.
• W1987193743 date "2006-02-08" @default.
• W1987193743 modified "2023-10-12" @default.
• W1987193743 title "Carbon Disulfide Reactions with Atomic Transition-Metal and Main-Group Cations: Gas-Phase Room-Temperature Kinetics and Periodicities in Reactivity" @default.
• W1987193743 cites W1983216704 @default.
• W1987193743 cites W1987701368 @default.
• W1987193743 cites W1991464692 @default.
• W1987193743 cites W1992045911 @default.
• W1987193743 cites W1998246830 @default.
• W1987193743 cites W2010751444 @default.
• W1987193743 cites W2013290868 @default.
• W1987193743 cites W2014479539 @default.
• W1987193743 cites W2018256404 @default.
• W1987193743 cites W2018392993 @default.
• W1987193743 cites W2021501024 @default.
• W1987193743 cites W2022337404 @default.
• W1987193743 cites W2031114124 @default.
• W1987193743 cites W2046009815 @default.
• W1987193743 cites W2054565285 @default.
• W1987193743 cites W2058880010 @default.
• W1987193743 cites W2059855495 @default.
• W1987193743 cites W2060588909 @default.
• W1987193743 cites W2065847284 @default.
• W1987193743 cites W2067266496 @default.
• W1987193743 cites W2075643964 @default.
• W1987193743 cites W2075709963 @default.
• W1987193743 cites W2087663030 @default.
• W1987193743 cites W2100906028 @default.
• W1987193743 cites W2122552034 @default.
• W1987193743 cites W2320808028 @default.
• W1987193743 cites W2950640657 @default.
• W1987193743 cites W2950934288 @default.
• W1987193743 cites W4242508380 @default.
• W1987193743 cites W572406511 @default.
• W1987193743 doi "https://doi.org/10.1021/jp057078s" @default.
• W1987193743 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/16494383" @default.
• W1987193743 hasPublicationYear "2006" @default.
• W1987193743 type Work @default.
• W1987193743 sameAs 1987193743 @default.
• W1987193743 citedByCount "46" @default.
• W1987193743 countsByYear W19871937432013 @default.
• W1987193743 countsByYear W19871937432014 @default.
• W1987193743 countsByYear W19871937432015 @default.
• W1987193743 countsByYear W19871937432016 @default.
• W1987193743 countsByYear W19871937432017 @default.
• W1987193743 countsByYear W19871937432020 @default.
• W1987193743 countsByYear W19871937432021 @default.
• W1987193743 countsByYear W19871937432022 @default.
• W1987193743 countsByYear W19871937432023 @default.
• W1987193743 crossrefType "journal-article" @default.
• W1987193743 hasAuthorship W1987193743A5039773551 @default.
• W1987193743 hasAuthorship W1987193743A5043332857 @default.
• W1987193743 hasAuthorship W1987193743A5043954197 @default.
• W1987193743 hasConcept C106773901 @default.
• W1987193743 hasConcept C113196181 @default.
• W1987193743 hasConcept C121332964 @default.
• W1987193743 hasConcept C123669783 @default.
• W1987193743 hasConcept C142724271 @default.
• W1987193743 hasConcept C145148216 @default.
• W1987193743 hasConcept C147789679 @default.
• W1987193743 hasConcept C148898269 @default.
• W1987193743 hasConcept C149635348 @default.
• W1987193743 hasConcept C161790260 @default.
• W1987193743 hasConcept C165176872 @default.
• W1987193743 hasConcept C178790620 @default.
• W1987193743 hasConcept C179104552 @default.
• W1987193743 hasConcept C181500209 @default.
• W1987193743 hasConcept C184779094 @default.
• W1987193743 hasConcept C185592680 @default.
• W1987193743 hasConcept C204787440 @default.
• W1987193743 hasConcept C2776910235 @default.
• W1987193743 hasConcept C2779607818 @default.
• W1987193743 hasConcept C41008148 @default.
• W1987193743 hasConcept C544153396 @default.
• W1987193743 hasConcept C58312451 @default.
• W1987193743 hasConcept C62520636 @default.
• W1987193743 hasConcept C71924100 @default.
• W1987193743 hasConcept C89031862 @default.
• W1987193743 hasConceptScore W1987193743C106773901 @default.
• W1987193743 hasConceptScore W1987193743C113196181 @default.
• W1987193743 hasConceptScore W1987193743C121332964 @default.
• W1987193743 hasConceptScore W1987193743C123669783 @default.
• W1987193743 hasConceptScore W1987193743C142724271 @default.
• W1987193743 hasConceptScore W1987193743C145148216 @default.
• W1987193743 hasConceptScore W1987193743C147789679 @default.
• W1987193743 hasConceptScore W1987193743C148898269 @default.
• W1987193743 hasConceptScore W1987193743C149635348 @default.
• W1987193743 hasConceptScore W1987193743C161790260 @default.
• W1987193743 hasConceptScore W1987193743C165176872 @default.
• W1987193743 hasConceptScore W1987193743C178790620 @default.
• W1987193743 hasConceptScore W1987193743C179104552 @default.
• W1987193743 hasConceptScore W1987193743C181500209 @default.
• W1987193743 hasConceptScore W1987193743C184779094 @default.
• W1987193743 hasConceptScore W1987193743C185592680 @default.

• next