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- W1987202633 abstract "The far infrared torsional oscillatory absorption of a nematic liquid crystal has been isolated for the first time free of higher frequency proper modes. This has been achieved using a molecule specially synthesised for this purpose with a dipole moment engineered perpendicular to the long axis so that torsional oscillation about this axis modulates this component only. The far infra-red power absorption of the liquid crystal in the isotropic, nematic, solid and supercooled conditions is therefore a Poley absorption, i.e. the torsional oscillation about the rigid long axis of the liquid crystal molecule itself. The effect of phase changes on a macroscopic level is to sharpen and intensify this absorption. This is clear evidence to the effect that phase changes in liquid crystals are cooperative phenomena, the molecular librational dynamics about the long axis are little different from those in a regular molecular liquid." @default.
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- W1987202633 date "1986-05-01" @default.
- W1987202633 modified "2023-09-26" @default.
- W1987202633 title "The Poley absorption in liquid crystals" @default.
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- W1987202633 doi "https://doi.org/10.1016/0167-7322(86)80020-4" @default.
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