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• W1987205196 abstract "Abstract Six multidentate nitrogen ligands, 2,6-bis(1,5-diphenyl-1H-pyrazol-3-yl)pyridine (L1), 2,6-bis(1-methyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L2), 2,6-bis(1,5-dimethyl-1H-pyrazol-3-yl)pyridine (L3), 2,6-bis(5-phenyl-1H-pyrazol-3-yl)pyridine (L4), 2,6-bis(1-p-triflurophenyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L5), and 2,6-bis(1- m -methylphenyl-5-phenyl-1H-pyrazol-3-yl)pyridine (L6) were synthesized and characterized. Their palladium complexes catalyzed Suzuki–Miyaura cross-coupling revealed that the catalytic activities of these complexes were in the order of PdCl 2 -L5 > PdCl 2 -L1 > PdCl 2 -L6 > PdCl 2 -L2 > PdCl 2 -L3 > PdCl 2 -L4. With a low Pd loading of 10 − 5  mol%, PdCl 2 -L1 showed a high activity. The turnover numbers (TONs) were up to 58,000,000 for 4-bromobenzotrifluoride." @default.
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• W1987205196 date "2012-12-01" @default.
• W1987205196 modified "2023-10-18" @default.
• W1987205196 title "PdCl2-2,6-bis(1,5-diphenyl-1H-pyrazol-3-yl)pyridine catalyzed Suzuki–Miyaura cross-coupling" @default.
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• W1987205196 doi "https://doi.org/10.1016/j.catcom.2012.10.009" @default.
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