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- W1987228162 abstract "Analog zu kürzlich [1, 2] mitgeteilten Untersuchungen über Nd(IV) in Sauerstoffperowskiten haben wir auch Dysprosium(IV) durch Einbau in Wirtsgitter mit Perowskit-struktur stabilisiert. Als Wirtsgitter wurden BaCeO3, BaTbO3 und SrTbO3 angeboten. Nur in Ba(Ce, Dy)O3 konnte mit Sicherheit Dy(IV) nachgewiesen werden. In den dargestellten Mischoxiden trat andererseits auch die Phase Ba3Dy4O9 auf. Es wurden die Gitterparameter dieser Verbindung und einiger zusammengesetzter Phasen neu bestimmt. Oxide Perovskites with Tetravalent Dysprosium and Compounds of the Type Ba3RE4O9 (RE = Rare Earth Element) In analogy to our investigations concerning tetravalent Nd in oxide perovskites [1, 2], we also tried to stabilize dysprosium(IV) by incorporation in host-lattices with the perovskite structure. As host-lattices we used BaCeO3, BaTbO3, and SrTbO3. Only in Ba(Ce, Dy)O3 we could trace Dy(IV) with certainty. Among the prepared mixed oxides, also the phase Ba3Dy4O9 occured. The lattice parameters of several phases of this latter type were redetermined." @default.
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- W1987228162 date "1980-03-01" @default.
- W1987228162 modified "2023-10-16" @default.
- W1987228162 title "�ber vierwertiges Dysprosium in Sauerstoff-Perowskiten und �ber Verbindungen des Formeltyps Ba3SE4O9 (SE = Selten-Erd-Element)" @default.
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- W1987228162 doi "https://doi.org/10.1002/zaac.19804620104" @default.
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