Matches in SemOpenAlex for { <https://semopenalex.org/work/W1987262078> ?p ?o ?g. }
- W1987262078 endingPage "7222" @default.
- W1987262078 startingPage "7210" @default.
- W1987262078 abstract "Interesting kinetic phenomena, such as multiple steady states and kinetic oscillations recently found in the NO+H2 reaction over Rh(533) and Rh(111) single crystal surfaces in the 10−6 mbar pressure range have been studied by means of experiments and computer modeling. A mathematical model, consisting of five ordinary differential equations and taking into account the lateral interactions in the adlayer, has been developed for simulating the NO+H2/Rh(533) and NO+H2/Rh(111) reactions. The simulation results make it possible to explain in detail the underlying reasons for the experimentally observed complex dynamic behavior. In particular, the kinetic oscillations and their properties have been reproduced. It was found that accumulation of NHads species, which serves as an intermediate in the pathway of NH3 production, is an important step in the oscillatory mechanism. In addition, the same mathematical model is able to successfully reproduce the experimental data concerning temperature programmed desorption (TPD) spectra, hysteresis phenomena, and the dependence of selectivity upon temperature and reactant partial pressures. Lateral interactions in the adlayer are shown to play a crucial role in the adequate simulation of the experimental observations." @default.
- W1987262078 created "2016-06-24" @default.
- W1987262078 creator A5019556003 @default.
- W1987262078 creator A5050826215 @default.
- W1987262078 creator A5063848110 @default.
- W1987262078 creator A5077492650 @default.
- W1987262078 creator A5090649646 @default.
- W1987262078 date "1996-10-22" @default.
- W1987262078 modified "2023-10-18" @default.
- W1987262078 title "Kinetic oscillations and hysteresis phenomena in the NO+H2 reaction on Rh(111) and Rh(533): Experiments and mathematical modeling" @default.
- W1987262078 cites W1964644328 @default.
- W1987262078 cites W1980028156 @default.
- W1987262078 cites W1983147857 @default.
- W1987262078 cites W1983636605 @default.
- W1987262078 cites W1995167146 @default.
- W1987262078 cites W1998243704 @default.
- W1987262078 cites W2000157733 @default.
- W1987262078 cites W2001606198 @default.
- W1987262078 cites W2002443268 @default.
- W1987262078 cites W2007006225 @default.
- W1987262078 cites W2012137576 @default.
- W1987262078 cites W2015572127 @default.
- W1987262078 cites W2029968361 @default.
- W1987262078 cites W2031201447 @default.
- W1987262078 cites W2034792020 @default.
- W1987262078 cites W2034965862 @default.
- W1987262078 cites W2036186208 @default.
- W1987262078 cites W2041672867 @default.
- W1987262078 cites W2041721770 @default.
- W1987262078 cites W2045505790 @default.
- W1987262078 cites W2049197897 @default.
- W1987262078 cites W2051641349 @default.
- W1987262078 cites W2053265088 @default.
- W1987262078 cites W2057795697 @default.
- W1987262078 cites W2058411866 @default.
- W1987262078 cites W2063011043 @default.
- W1987262078 cites W2067449132 @default.
- W1987262078 cites W2071885231 @default.
- W1987262078 cites W2074933229 @default.
- W1987262078 cites W2078542418 @default.
- W1987262078 cites W2083897412 @default.
- W1987262078 cites W2092563541 @default.
- W1987262078 cites W2102927406 @default.
- W1987262078 cites W2312475398 @default.
- W1987262078 cites W3180042145 @default.
- W1987262078 cites W4254613696 @default.
- W1987262078 doi "https://doi.org/10.1063/1.472524" @default.
- W1987262078 hasPublicationYear "1996" @default.
- W1987262078 type Work @default.
- W1987262078 sameAs 1987262078 @default.
- W1987262078 citedByCount "38" @default.
- W1987262078 countsByYear W19872620782013 @default.
- W1987262078 countsByYear W19872620782016 @default.
- W1987262078 countsByYear W19872620782020 @default.
- W1987262078 crossrefType "journal-article" @default.
- W1987262078 hasAuthorship W1987262078A5019556003 @default.
- W1987262078 hasAuthorship W1987262078A5050826215 @default.
- W1987262078 hasAuthorship W1987262078A5063848110 @default.
- W1987262078 hasAuthorship W1987262078A5077492650 @default.
- W1987262078 hasAuthorship W1987262078A5090649646 @default.
- W1987262078 hasConcept C121332964 @default.
- W1987262078 hasConcept C123299182 @default.
- W1987262078 hasConcept C135889238 @default.
- W1987262078 hasConcept C147789679 @default.
- W1987262078 hasConcept C148898269 @default.
- W1987262078 hasConcept C150394285 @default.
- W1987262078 hasConcept C159467904 @default.
- W1987262078 hasConcept C162711632 @default.
- W1987262078 hasConcept C185592680 @default.
- W1987262078 hasConcept C26873012 @default.
- W1987262078 hasConcept C74650414 @default.
- W1987262078 hasConcept C8265204 @default.
- W1987262078 hasConcept C97355855 @default.
- W1987262078 hasConceptScore W1987262078C121332964 @default.
- W1987262078 hasConceptScore W1987262078C123299182 @default.
- W1987262078 hasConceptScore W1987262078C135889238 @default.
- W1987262078 hasConceptScore W1987262078C147789679 @default.
- W1987262078 hasConceptScore W1987262078C148898269 @default.
- W1987262078 hasConceptScore W1987262078C150394285 @default.
- W1987262078 hasConceptScore W1987262078C159467904 @default.
- W1987262078 hasConceptScore W1987262078C162711632 @default.
- W1987262078 hasConceptScore W1987262078C185592680 @default.
- W1987262078 hasConceptScore W1987262078C26873012 @default.
- W1987262078 hasConceptScore W1987262078C74650414 @default.
- W1987262078 hasConceptScore W1987262078C8265204 @default.
- W1987262078 hasConceptScore W1987262078C97355855 @default.
- W1987262078 hasIssue "16" @default.
- W1987262078 hasLocation W19872620781 @default.
- W1987262078 hasOpenAccess W1987262078 @default.
- W1987262078 hasPrimaryLocation W19872620781 @default.
- W1987262078 hasRelatedWork W1522943768 @default.
- W1987262078 hasRelatedWork W1989280951 @default.
- W1987262078 hasRelatedWork W2005867420 @default.
- W1987262078 hasRelatedWork W2015321541 @default.
- W1987262078 hasRelatedWork W2016698611 @default.
- W1987262078 hasRelatedWork W2026768347 @default.
- W1987262078 hasRelatedWork W2041362715 @default.
- W1987262078 hasRelatedWork W2067497128 @default.