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- W1987264199 abstract "The 35Cl n.q.r. spectra of a series of chlorine-containing phosphorus–nitrogen compounds including [Cl(X)PNR]2(X = lone pair, R = But; X = O, R = But or Me), PCl2(NButH)O, Cl2P·NBut·PCl2, Cl2P·NMe·P(O)Cl2, Cl2(X)P·NMe·P(X)Cl2(X = O or S), Cl2(O)P·NR·P(S)Cl2(R = Me or Ph), the heterocycle C17H20ClN2OP (see Table 1), and Cl2(O)P·N:PPh3 have been recorded at ambient temperatures and/or 77 K. The results are discussed in terms of the structures, where known, and a linear correlation between P–Cl bond lengths and n.q.r. frequencies has been deduced for phosphoryl compounds : this is different from the correlation previously deduced for cyclophosphazenes. Data for Cl2(O)PCH2P(O)Cl2 are also included. The n.q.r. results enable some comparisons to be made of the relative electron supply of some common substituents encountered in phosphorus chemistry." @default.
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- W1987264199 date "1977-01-01" @default.
- W1987264199 modified "2023-09-23" @default.
- W1987264199 title "Chlorine-35 nuclear quadrupole resonance studies of some chlorine-containing phosphorus–nitrogen compounds" @default.
- W1987264199 doi "https://doi.org/10.1039/dt9770001505" @default.
- W1987264199 hasPublicationYear "1977" @default.
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