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- W1987284908 abstract "The syntheses and characterization of heterobimetallic ‘early-late’ complexes containing the (tC4H9O)3Ti unit combined with the fragments [CPMo(CO)3], [Mn(CO)5] and [CpFe(CO)2] are described. [(tC4H9O)3Ti-Mn(CO)5] crystallizes in the monoclinic space group P21/c, with a = 11.418(2), b = 10.631(2), c = 19.136(2) Å, β = 96.02(1)° and Z = 4. The electronic structures and differences in stabilities of complexes [(tC4H9O)3Ti-Mn(CO)5], [(tC4H9O)3Ti-Co(CO)4] and [(tC4H9O)3Ti-Co(CO)3PPh3] are discussed on the basis of EHMO calculations. Die Synthese and Charakterisierung heterobimetallischer ‘early-late’ Komplexe, die die Einheit (tC4H9O)3Ti an die Komplexfragmente [CpMo(CO)3], [Mn(CO)5] and [CpFe(CO)2] gebunden enthalten, wird beschrieben. Bei 213 K untersuchte Kristalle des [(tC4H9O)3Ti-Mn(CO)5] sind monoklin, Raumgruppe P21/c, with a = 11.418(2), b = 10.631(2), c = 19.136(2) Å, β = 96.02(1)° und Z = 4. Die Elektronenstrukturen and Stabilitätsunterschiede von [(tC4H9O)3Ti-Mn(CO)5], [tC4H9O)3TiCo(CO)4] und [tC4H9O)3TiCo(CO)3PPh3] werden auf der Basis von EHMO-Rechnungen diskutiert." @default.
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- W1987284908 date "1995-10-01" @default.
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- W1987284908 title "Synthese und charakterisierung heterobimetallischer komplexe des typs [(t C4H9O)3Ti-MLn] (MLn = CPMo(CO)3, CpFe(CO)2, Mn(CO)5). Einkristallröntgenstrukturanalyse von [(tC4H9O)3Ti-Mn(CO)5] bei 213 K. Extended Hückel MO-Rechnungen an[(tC4H9O) 3Ti-Mn(CO)5] und [(tC4H9O)3Ti-Co(CO)3L] (L = CO, PPh3)" @default.
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- W1987284908 doi "https://doi.org/10.1016/0022-328x(95)05674-e" @default.
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