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• W1987289326 endingPage "261" @default.
• W1987289326 startingPage "247" @default.
• W1987289326 abstract "A survey of the conceptions related to the model of two parallel condensers and to the difference in behaviour of the surface potential at electrodes and at free surfaces is presented, emphasizing the aspects remaining not fully clarified. It is shown, using elementary electrostatics, that the permittivity value entering into the expression of the Helmholtz formula may vary with the surface density of polar surfactants. The consistency of the model of two parallel condensers is improved if this effect is taken into account. The possible effects of imaging and of displacement of water molecules from the surface are discussed. The effective permittivity and the effective dipole moment can be evaluated from available data. The values found for these parameters in the case of aliphatic alcohols support the analysis which depending on the coverage in the case of electrodes, while at free surfaces, the effective permittivity is equal to twice the value for the vacuum." @default.
• W1987289326 created "2016-06-24" @default.
• W1987289326 creator A5073503834 @default.
• W1987289326 date "1986-04-01" @default.
• W1987289326 modified "2023-09-25" @default.
• W1987289326 title "The model of two parallel condensers and the application of the Helmholtz formula to adsorption of polar surfactants from aqueous solutions" @default.
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• W1987289326 doi "https://doi.org/10.1016/0022-0728(86)80053-5" @default.
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