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- W1987291228 startingPage "2361" @default.
- W1987291228 abstract "The two trifunctional ligands 2,6-(Ph,P(O)—CH2)2C5H3NO (1) and 2,6[(EtO)2P(O)—CH2]2C5H3NO (2) were prepared by Arbuzov reactions on 2,6-bis (chloromethyl)pyridine with Ph2POMe and triethylphosphite, respectively, and characterized by spectroscopic methods and X-ray structural analysis (1). Their coordination chemistry with Bi(NO3)3 was studied. The complexes Bi(NO3)3·1·DMF and Bi (N03)3·2 were isolated and their X-ray structures determined. In both cases, the ligands bind in a tridentate fashion to BiIII, and the nitrate ions remain in the inner coordination sphere. Structural features of the unbound and bound ligand I are discussed." @default.
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- W1987291228 date "1995-08-01" @default.
- W1987291228 modified "2023-10-16" @default.
- W1987291228 title "Synthesis and molecular structures of complexes of bismuth(III) nitrate with tridentate ligands : 2,6-BIS(-CH2 P((O)R2) substituted pyridine-N-oxides" @default.
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- W1987291228 doi "https://doi.org/10.1016/0277-5387(95)00061-v" @default.
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