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- W1987295328 abstract "Diastereomeric disiloxane-1,3-diols, 1, with two asymmetric silicon centers and intramolecular coordination arms were synthesized and separated manually. They show distinguishing structural features such as a linear or bent Si−O−Si skeleton, a short Si−O bond length, and strong intramolecular hydrogen bonding. A trace of water induced the diastreomeric isomerization of 1 under noncatalytic conditions, while the anhydrous disiloxane-1,3-diols were stereochemically stable." @default.
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- W1987295328 date "2002-09-13" @default.
- W1987295328 modified "2023-09-26" @default.
- W1987295328 title "Water-Induced Diastereomeric Isomerization of Novel Disiloxane-1,3-diols Separated Manually" @default.
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- W1987295328 doi "https://doi.org/10.1021/om020427+" @default.
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