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• W1987295587 endingPage "3631" @default.
• W1987295587 startingPage "3625" @default.
• W1987295587 abstract "Abstract Cis–transoidal poly[(4‐carboxyphenyl)acetylene] (poly‐ 1 ) complexed with optically active amines and amino alcohols showed an induced circular dichroism (ICD) in the ultraviolet–visible region because of a predominantly one‐handed helix formation in water and in dimethyl sulfoxide (DMSO). The Cotton effect signs of the poly‐ 1 /chiral amino alcohol complexes were inverted in the presence of water, whereas the ICD pattern of the poly‐ 1 /chiral amine complexes showed no change, regardless of the water content. These results demonstrated that the helix sense of poly‐ 1 induced by optically active amino alcohols through noncovalent acid–base interactions could be switched by changes in the solvent ratio in the DMSO–water mixtures. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 3625–3631, 2003" @default.
• W1987295587 created "2016-06-24" @default.
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• W1987295587 date "2003-10-08" @default.
• W1987295587 modified "2023-10-17" @default.
• W1987295587 title "Solvent‐induced switching of the macromolecular helicity of poly[(4‐carboxyphenyl)acetylene] induced by a single chiral amino alcohol" @default.
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• W1987295587 doi "https://doi.org/10.1002/pola.10841" @default.
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