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- W1987298506 abstract "Fe(III) hydroxide gels were produced from a series of 0·5 molal Fe(III) nitrate solutions hydrolyzed for varying times and at pH values up to 1·5. The types and sizes of crystals produced by aging the gels at 60°C in the presence of excess NaOH were examined qualitatively by electron microscopy, selected area diffraction and X-ray diffractometry. Acicular goethite crystals were nucleated in the gel by extremely small goethite crystals which had formed during slow hydrolysis in the parent iron solution. Goethite crystals occurred as cruciform twins showing an apparent (021) twin plane when epitaxial growth commenced on nuclei which were extremely small crystals of hematite formed during very rapid hydrolysis at precipitation. According to conditions of pH the hematite nuclei grew to hematite, to hematite with epitaxial growths of goethite, or to twinned goethite crystals apparently free of hematite." @default.
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- W1987298506 date "1968-09-01" @default.
- W1987298506 modified "2023-10-17" @default.
- W1987298506 title "Crystal nucleation in Fe(III) solutions and hydroxide gels" @default.
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- W1987298506 doi "https://doi.org/10.1016/0022-1902(68)80247-7" @default.
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