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- W1987307498 abstract "The role of basicity in the surface reactions of amines has been investigated in an STM/XPS study of the oxidation of methylamine, ethylamine and 2,2,2-trifluoroethylamine at a Cu(1 1 0) surface. Methylamine and ethylamine are strongly basic molecules and for sub monolayer concentrations of oxygen form an amine/oxygen complex characterised by a (3 × 1) structure. The complex rapidly decomposes at room temperature to form water and an imide which desorbs via β-elimination. In contrast, 2,2,2-trifluoroethylamine has a relatively low basicity and its reactions with surface oxygen do not involve a stable intermediate." @default.
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- W1987307498 date "2007-08-01" @default.
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- W1987307498 title "Molecularly resolved studies of the role of basicity in the reaction of amines with oxygen at a Cu(110) surface" @default.
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- W1987307498 doi "https://doi.org/10.1016/j.susc.2007.06.009" @default.
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