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- W1987316123 abstract "New macromolecular self-assembling building blocks, star polypeptide-b-polyhedral oligomeric silsesquioxane (POSS) copolymers, were synthesized from octa-azido functionalized POSS (OVBN3-POSS) with alkyne-poly(γ-benzyl-l-glutamate) (alkyne-PBLG) via a click reaction. The incorporation of POSS units at the core of PBLG moieties plays an important role, allowing intramolecular hydrogen bonding between the POSS and PBLG units to enhance the α-helical conformations in the solid state based on Fourier Transform Infrared spectroscopy (FTIR), solid state nuclear magnetic resonance (NMR), and wide-angle X-ray diffraction (WAXD) analyses." @default.
- W1987316123 created "2016-06-24" @default.
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- W1987316123 date "2010-11-01" @default.
- W1987316123 modified "2023-09-26" @default.
- W1987316123 title "Control of peptide secondary structure on star shape polypeptides tethered to polyhedral oligomeric silsesquioxane nanoparticle through click chemistry" @default.
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- W1987316123 doi "https://doi.org/10.1016/j.polymer.2010.10.005" @default.
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