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- W1987328020 abstract "Der Rhenium(V)nitrido-Komplex (PPh4)3[Re2NCl10] (1) entsteht bei der Reaktion von (PPh4)[ReNCl4] mit 1, 3-Dioxan-(2-ylmethyl)diphenylphosphan in CH2Cl2/CH3CN in Form orangeroter, solvathaltiger Kristalle. Er kristallisiert als 1·2CH2Cl2 in der triklinen Raumgruppe P1¯ mit a = 1210, 7(2); b = 1232, 5(1); c = 2756, 3(5) pm; α = 99, 68(1)°; β = 100, 24(1)°; γ = 98, 59(1)° und Z = 2. In der Kristallstruktur liegen zwei symmetrieunabhängige, zentrosymmetrische Komplexanionen [Re2NCl10]3- mit symmetrischen Nitridobrücken Re=N=Re und Abständen Re(1) - N(1) = 181, 34(5) und Re(2) - N(2) = 181, 51(4) pm vor. Synthesis and Crystal Structure of (PPh4)3[Re2NCl10] The rhenium(V) nitrido complex (PPh4)3[Re2NCl10] (1) is obtained from the reaction of (PPh4)[ReNCl4] with 1, 3-dioxan-(2-ylmethyl)diphenyl phosphine in CH2Cl2/CH3CN in form of orange red crystals with the composition 1·2CH2Cl2 crystallizing in the triclinic space group P1¯ with a = 1210.7(2), b = 1232.5(1), c = 2756.3(5) pm, α = 99.68(1)°, β = 100.24(1)°, γ = 98.59(1)° and Z = 2. The crystal structure contains two symmetry independent, centrosymmetrical complex anions [Re2NCl10]3- with a symmetrical nitrido bridge Re=N=Re and distances Re(1) - N(1) = 181.34(5) and Re(2) - N(2) = 181.51(4) pm." @default.
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- W1987328020 date "2004-12-01" @default.
- W1987328020 modified "2023-09-27" @default.
- W1987328020 title "Synthese und Struktur von (PPh4)3[Re2NCl10]" @default.
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- W1987328020 doi "https://doi.org/10.1002/zaac.200400374" @default.
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