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• W1987335874 abstract "The copper-chalcogenolates [(Me 3 SiE-Cu) 2 (µ-Ph 2 PC[Formula: see text]CPPh 2 -κ 2 P) 3 ] (1, E = S; 2, E = Se; 3, E = Te) have been prepared in good yield from [(OAcCu) 2 (µ-Ph 2 PC[Formula: see text]CPPh 2 -κ 2 P) 3 ] and E(SiMe 3 ) 2 at low temperatures. Complexes 1–3 contain two pendant -ESiMe 3 moieties bonded to copper(I) centres, which are also bridged by three didentate ligands to form helical structures. Complexes 1–3 have been characterized by single crystal crystallographic and spectroscopic methods.Key words: copper, chalcogen, helical, trimethylsilyl groups, phosphinoacetylene." @default.
• W1987335874 created "2016-06-24" @default.
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• W1987335874 date "2002-11-01" @default.
• W1987335874 modified "2023-10-18" @default.
• W1987335874 title "Triply bridged dicopper-bis(trimethylsilylchalcogenolates): Synthesis and characterization of the series of helical complexes [(Me₃SiE-Cu)₂(µ-Ph₂PCCPPh₂-κ²<i>P</i>)₃] (E = S, Se, Te)" @default.
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• W1987335874 doi "https://doi.org/10.1139/v02-032" @default.
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