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- W1987359080 abstract "The overall rate of reaction of p-methoxybenzyl chloride with 70% aqueous acetone is increased by the addition of pyridine but the rate of hydrolysis is decreased. Comparison of these data with those for benzhydryl chloride under the same conditions shows that the rate of hydrolysis of p-methoxybenzyl chloride is less than the rate of ionisation. These results are discussed in terms of concurrent operation of the S N 1 mechanism and a bimolecular process. Similar results are obtained when thiourea is used instead of pyridine." @default.
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- W1987359080 date "1979-10-01" @default.
- W1987359080 modified "2023-09-29" @default.
- W1987359080 title "The mechanism of the solvolysis of <i>p</i>-methoxybenzyl chloride in aqueous acetone containing pyridine or thiourea. Evidence for concurrent substitution by unimolecular and bimolecular processes" @default.
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- W1987359080 doi "https://doi.org/10.1139/v79-429" @default.
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