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- W1987362018 abstract "Tricyclo(4.2.2.o1,5)decane (7) in the presence of AlBr3 rearranges partly “forwards” to adamantane (1) and partly “backwards” to tetrahydrodicyclopentadiene (2, largely the oxo isomer). Intermediate 14, characterizing the 7→exo-8→14→3→1 forward pathway, is found only in small amounts. The detection of a new intermediate, 12, also shows that a second major rearrangement route from 7 to 1 is being utilized (see dashed lines in Figure 1)." @default.
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- W1987362018 date "1980-01-01" @default.
- W1987362018 modified "2023-10-18" @default.
- W1987362018 title "An adamantane rearrangement. A new pathway" @default.
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- W1987362018 doi "https://doi.org/10.1016/s0040-4039(00)77739-2" @default.
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